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John Robison (1739–1805), FRSE c.1798 Henry Raeburn (1756–1823)John Robison (1739–1805), FRSE c.1798 The Royal Society of Edinburgh
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Allan Maconochie (1748–1816), Lord Meadowbank 1812 Francis Leggatt Chantrey (1781–1841)Allan Maconochie (1748–1816), Lord Meadowbank 1812 The Royal Society of Edinburgh
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Sir Humphrey Davy (1778–1829), Bt, FRS, FRSE c.1821–1822 James Lonsdale (1777–1839) (attributed to)Sir Humphrey Davy (1778–1829), Bt, FRS, FRSE c.1821–1822 The Royal Society of Edinburgh
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James Gregory (1753–1821) 1821 Samuel Joseph (1791–1850)James Gregory (1753–1821) 1821 The Royal Society of Edinburgh
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Baron Jöns Jacob Berzelius (1779–1848) 1822 Christian Friedrich Tieck (1776–1851)Baron Jöns Jacob Berzelius (1779–1848) 1822 The Royal Society of Edinburgh
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James Watt (1736–1819), FRSE c.1828 William Beechey (1753–1839) (copy of)James Watt (1736–1819), FRSE c.1828 The Royal Society of Edinburgh
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Sir Walter Scott (1771–1832), Bt, FRSE 1829 John Graham-Gilbert (1794–1866)Sir Walter Scott (1771–1832), Bt, FRSE 1829 The Royal Society of Edinburgh
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Henry Scott (1746–1812), 3rd Duke of Buccleuch and 5th Duke of Queensberry, FRSE 1830 John Watson Gordon (1788–1864)Henry Scott (1746–1812), 3rd Duke of Buccleuch and 5th Duke of Queensberry, FRSE 1830 The Royal Society of Edinburgh
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Patrick Neill (1776–1851), FRSE 1837 or before John Syme (1795–1861)Patrick Neill (1776–1851), FRSE 1837 or before The Royal Society of Edinburgh
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Sir John Sinclair of Ulbster (1754–1835) 1832 John Greenshields (1795–1835)Sir John Sinclair of Ulbster (1754–1835) 1832 The Royal Society of Edinburgh
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John Napier of Merchiston (1550–1617) 1841 Peter Slater (1809–1870)John Napier of Merchiston (1550–1617) 1841 The Royal Society of Edinburgh
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Professor John Playfair (1748–1819) 1845 Francis Leggatt Chantrey (1781–1841) (after)Professor John Playfair (1748–1819) 1845 The Royal Society of Edinburgh
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James Hutton (1726–1797) c.1850 Patric Park (1811–1855)James Hutton (1726–1797) c.1850 The Royal Society of Edinburgh
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Sir Thomas Makdougall Brisbane (1773–1860), Bt, FRSE 1848 John Watson Gordon (1788–1864)Sir Thomas Makdougall Brisbane (1773–1860), Bt, FRSE 1848 The Royal Society of Edinburgh
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Sir Thomas Makdougall Brisbane (1773–1860) c.1854 James Gall (1808–1895) (after)Sir Thomas Makdougall Brisbane (1773–1860) c.1854 The Royal Society of Edinburgh
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James David Forbes (1809–1868), FRSE 1860/1861 John Watson Gordon (1788–1864)James David Forbes (1809–1868), FRSE 1860/1861 The Royal Society of Edinburgh
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Sir David Brewster (1781–1868), FRSE 1869 Norman Macbeth (1821–1888)Sir David Brewster (1781–1868), FRSE 1869 The Royal Society of Edinburgh
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David Hume (1711–1776) late 19th C James Pittendrigh MacGillivray (1856–1938)David Hume (1711–1776) late 19th C The Royal Society of Edinburgh
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Sir Roderick Impey Murchison (1792–1871) 1871 Henry Weekes I (1807–1877)Sir Roderick Impey Murchison (1792–1871) 1871 The Royal Society of Edinburgh
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Sir Robert Christison (1797–1882), Bt, FRSE 1874/1875 George Reid (1841–1913)Sir Robert Christison (1797–1882), Bt, FRSE 1874/1875 The Royal Society of Edinburgh